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Cluster Expanded Prussian Blue Analogues Journal of the

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Preparation of Copper-iron Hexacyanoferrate Loaded Multi .

Poly(3,4-ethylenedioxythiophene) and Prussian Blue Analogues[J]. Electrochim Acta,2011,56(10) ... Fabrication and Photoelectrocatalysis Performance of Expanded[J]. ...

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Single-crystal X-ray diffraction analyses show that compounds 1, 2, 5, and 6 have distorted face-centered-cubic frameworks that can be considered as superexpanded Prussian blue analogues built of two different hexacyanometallate nodes and expanded by insertion of the [Mn(salen)](+) complex, while 4 features a quasi-superexpanded Prussian blue ...

Matthew P. Shores - Publicatio

71 high-probability publications. We are testing a new system for linking publications to authors. You can help! If you notice any inaccuracies, please sign in and mark papers as correct or incorrect matches. If you identify any major omissions or other inaccuracies in the publication list, please let us know.

Synthesis And Characterization of Prussian Blue Analogues .

OSTI.GOV Journal Article: Synthesis And Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr(6)BCl(12)]**2+ Cluster Core. Synthesis And Characterization of Prussian Blue Analogues Incorporating the Edge-Bridged Octahedral [Zr(6)BCl(12)]**2+ Cluster Core. Full Record;

Single-crystal-to-single-crystal intercalation of a low .

The controlled introduction of impurities into the crystal lattice of solid-state compounds is a cornerstone of materials science. Intercalation, the insertion of guest atoms, ions or molecules ...

... of the octahedral cyano-bridged cluster complex β-[{Ni .

The rhenium atoms of the {Re6Te8} cluster core are coordinated by CN ligands to form the [Re6Te8(CN)6] ... Journal Journal of structural chemistry SCI(E) SCOPUS ...

Cluster-Expanded Prussian Blue Analogues | Journal of the .

A method for expanding the pores in crystalline frameworks is demonstrated with the substitution of face-capped octahedral [Re6Q8(CN)6]4- (Q = Se, Te) clusters into the Prussian blue structure. The clusters react in aqueous solution with Ga3+ and Fe3+, respectively, to precipitate Ga4[Re6Se8(CN)6]3·xH2O and Fe4[Re6Te8(CN)6]3·xH2O. Rietveld analysis of X-ray powder diffraction data for the ...

Expanded Prussian Blue Analogues Incorporating [Re Se (CN .

out of every three cluster hexacyanide units missing as a consequence of charge balance. In contrast, reaction of [Ga(H2O)6]3+ with 3 gives Ga[Re6Se8(CN)6]â6H2O(7), wherein charge balance dictates a fully occupied cubic framework enclosing much smaller cavities. The expanded Prussian blue analogues 4-7 can be fully

Functional Electrocatalysts Derived from Prussian Blue and .

PB (Fe III 4 [Fe II (CN) 6] 3) is an ancient pigment discovered in the 18th century and comprised of Fe 3+ /Fe 2+ bridged by cyano group. 32 By substituting iron element with other transition metals such as cobalt, nickel, manganese, copper and zinc, various Prussian blue analogues (PBAs) with distinct chemical compositions yet similar crystal ...

Photomagnetism - Wikiped

In this case the iron molecules are randomly replaced by water (6 molecules of water per replaced iron). This non-stoichiometric is essential to the photomagnetism of Prussian blue analogues as regions which contain an iron vacancy are more stable in the non magnetic state and regions without a vacancy are more stable in the magnetic state.

Synthesis and characterization of Prussian blue analogues .

In attempts to produce a microporous magnet, two approaches were explored for expanding the Prussian blue structure type via incorporation of edge-bridged octahedral [Zr(6)ZCl(12)](2+) (Z = B, Be) cluster cores.

Self-Assembly of Cluster-Based Nanoscopic Supramolecules .

Self-Assembly of Cluster-Based Nanoscopic Supramolecules into One-Dimensional Coordination Polymers. Advances in Materials Science and Engineering, Oct 2009 Jian-Jun Zhang, Sergio Aarón Gamboa, Barry Julian Davis, Abdessadek Lachgar. Jian-Jun Zhang. Sergio Aarón Gamboa ...

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Professor, PhD, PhD supervisor, as the dean of the School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, P. R. China.Vice Chairman of Jia

Advances in Materials Science and Engineering - Hinda

Advances in Materials Science and Engineering is a peer-reviewed, Open Access journal that publishes original research articles as well as review articles in all areas of materials science and engineering. ... and J. R. Long, “Expanded Prussian blue analogues incorporating [Re 6 Se 8 (CN) 6] 3 ...

CrystEngComm - pubs.rsc.o

Compared to ‘ superexpanded Prussian-blue analogue ‘, the cations and the anions in 1 as well as their topological roles of node and spacer are permuted that allows us to call this structure type anti-Prussian blue. Experimental Materials and spectroscopic studies The starting cluster salt CaK 4[Re 3Mo 3S8(CN) 6]·8H 2O was prepared as ...

Chemistry Tree - Matthew P. Shor

You can help our author matching system! If you notice any publications incorrectly attributed to this author, please sign in and mark matches as correct or incorrect. Ozumerzifon TJ, Higgins RF, Joyce JP, et al. (2019) Evidence for Reagent-Induced Spin-State Switching in Tripodal Fe(II) Iminopyridine Complexes.Inorganic Chemistry

Cluster-Expanded Prussian Blue Analogues - Journal of the .

Cluster-Expanded Prussian Blue Analogues Matthew P. Shores , Laurance G. Beauvais , and Jeffrey R. Long * Contribution from the Department of Chemistry, University of California, Berkeley, California 94720-1460

Magnetism and Photomagnetism of Prussian Blue Analogue .

Prussian blue analogues (PBAs) are key compounds in the field of molecular magnetism and photomagnetism. In parallel to the strong development of this class of compounds, many efforts have been devoted to produce PBAs in various shapes and sizes.

Chemistry – A European Journal : Vol 24 , No

Electrochemical studies were performed on a series of Prussian blue analogues (PBAs), Co x [M(CN) 6] y (M=Fe 2+/3+, Cr 3+, and Co 3+), to study the effect of neighboring metal ions on the electronic properties of catalytically active cobalt sites.The experimental and computational studies indicate that the nucleophilic attack of water to cobalt‐oxo species should be the rate‐determining ...

Expanded Prussian Blue Analogues Incorporating[Re(6)Se(8 .

Expanded Prussian Blue Analogues Incorporating[Re(6)Se(8 ...

Synthesis, crystal structure and characterization of a 2-D .

Synthesis, crystal structure and characterization of a 2-D network organic-inorganic hybrid polymer with [α-BW 12 O 40] 5− as building blocks